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Chemical equilibrium. In a chemical reaction, chemical equilibrium is the state in which both the reactants and products are present in concentrations which have no further tendency to change with time, so that there is no observable change in the properties of the system. [ 1] This state results when the forward reaction proceeds at the same ...
Equilibrium chemistry is concerned with systems in chemical equilibrium. The unifying principle is that the free energy of a system at equilibrium is the minimum possible, so that the slope of the free energy with respect to the reaction coordinate is zero. [ 1][ 2] This principle, applied to mixtures at equilibrium provides a definition of an ...
Law of mass action. In chemistry, the law of mass action is the proposition that the rate of a chemical reaction is directly proportional to the product of the activities or concentrations of the reactants. [ 1] It explains and predicts behaviors of solutions in dynamic equilibrium. Specifically, it implies that for a chemical reaction mixture ...
a thermodynamic equilibrium constant, denoted by , is defined to be the value of the reaction quotient Qt when forward and reverse reactions occur at the same rate. At chemical equilibrium, the chemical composition of the mixture does not change with time, and the Gibbs free energy change for the reaction is zero.
A solubility equilibrium exists when a chemical compound in the solid state is in chemical equilibrium with a solution containing the compound. This type of equilibrium is an example of dynamic equilibrium in that some individual molecules migrate between the solid and solution phases such that the rates of dissolution and precipitation are equal to one another.
Calorimetry – The study of heat changes in physical and chemical processes. Organic chemistry ( outline) – study of the structure, properties, composition, mechanisms, and reactions of organic compounds. An organic compound is defined as any compound based on a carbon skeleton.
The reaction quotient is a powerful concept in chemical kinetics and thermodynamics, enabling the prediction of reaction directions, the extent of reaction progress, and the determination of equilibrium constants. It finds applications in various fields, including chemical engineering, biochemistry, and environmental chemistry, where ...
A chemical property is any of a material's properties that becomes evident during, or after, a chemical reaction; that is, any quality that can be established only by changing a substance's chemical identity. [ 1] Simply speaking, chemical properties cannot be determined just by viewing or touching the substance; the substance's internal ...